Azobisisobutyronitrile CAS#78-67-1

Controlled and Reliable Radical Generation: It decomposes at a moderate temperature with well-defined kinetics, enabling predictable and reproducible initiation performance in polymerization processes.

Clean Decomposition without Residues: Unlike peroxide initiators, it releases only nitrogen gas upon decomposition, leaving no acidic or oxygen-containing by-products that could impair product quality.

Broad Applicability across Polymer Systems: It works efficiently in bulk, suspension and solution polymerization of styrene, acrylonitrile, vinyl chloride and acrylic esters, and also serves as a blowing agent and synthetic radical source.

Easy Handling with Storage Reliability: Being a stable, free-flowing crystalline powder with good solubility in common organic media, it offers convenient dosing while maintaining consistent quality under proper refrigerated storage.

Product Description of Azobisisobutyronitrile CAS#78-67-1

Azobisisobutyronitrile CAS#78-67-1, commonly known as AIBN, is a white columnar crystals or powder with a molecular formula of C₈H₁₂N₄ and a molecular weight of 164.21. It is an azo‑type compound that is thermally sensitive and decomposes upon heating, releasing nitrogen gas and generating free radicals. 

Because of its self‑reactive nature, it must be stored in a cool, dark and well‑ventilated place, preferably under refrigeration, and kept away from heat, sparks, friction and strong oxidizing agents. 

2,2-Azobis(2-methylpropionitrile) CAS#78-67-1

Azobisisobutyronitrile Chemical Properties

Melting point 102-104 °C (dec.)(lit.)
Boiling point 281.68°C (rough estimate)
density 1.11
vapor pressure 0.81Pa at 24.85℃
refractive index n20/D1.495
Fp 4℃
storage temp. 2-8°C
solubility Chloroform (Slightly), Methanol (Slightly)
form Solid
color Crystals from EtOH
Odorodorless
Water Solubility Insoluble
Merck 13920
BRN 1708400
Stability:Stability Flammable solid. Shock sensitive. Thermally unstable. May be explosive in combination with acetone or heptane. Incompatible with oxidizing agents.
InChIKeyOZAIFHULBGXAKX-VAWYXSNFSA-N
LogP1.1 at 25℃
CAS DataBase Reference78-67-1(CAS DataBase Reference)
NIST Chemistry Reference2,2'-Azo-bis-isobutyronitrile(78-67-1)
EPA Substance Registry SystemAzobis(isobutyronitrile) (78-67-1)
Hazard Codes E,Xn,F,Xi
Risk Statements 2-11-20/22-52/53-67-65-48/20-38-63-66-36
Safety Statements 39-41-47-61-62-36/37-16-26
RIDADR UN 3234 4.1
WGK Germany 2
RTECS UG0800000
F 4.4
HazardClass 4.1
PackingGroup II
HS Code 29269090
Hazardous Substances Data78-67-1(Hazardous Substances Data)
ToxicityLDLo orl-rat: 670 mg/kg 34ZIAG 0,117,69
2,2-Azobis(2-methylpropionitrile) CAS#78-67-1

Product Application of Azobisisobutyronitrile CAS#78-67-1

The substance frequently serves as a polymerization trigger for raw-material monomers covering vinyl chloride, vinyl acetate and acrylonitrile. When manufactured into rubber and plastic goods, it functions as a foaming additive with the recommended addition proportion kept between 10 percent and 20 percent.

Apart from the above-mentioned purposes, it may act as a rubber cross-linking reagent, alongside being a synthetic precursor for agro-chemicals and organic-chemistry work.

Great caution is needed for its manipulation owing to its acute toxicity. Its oral-administration LD50 value for mice falls within 17.2-25 mg/kg. Hazardous cyanide-containing organic substances will be generated after thermal breakdown, which poses serious health threats to human bodies.

2,2-Azobis(2-methylpropionitrile) CAS#78-67-1

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